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CC@BCN@PANI core-shell nanoarrays as ultra-high cycle stability cathode for Zn-ion hybrid supercapacitors

《能源前沿（英文）》 2023年 第17卷 第4期   页码 555-566 doi: 10.1007/s11708-023-0882-8

摘要： Exploring cathode materials that combine excellent cycling stability and high energy density poses a challenge to aqueous Zn-ion hybrid supercapacitors (ZHSCs). Herein, polyaniline (PANI) coated boron-carbon-nitrogen (BCN) nanoarray on carbon cloth surface is prepared as advanced cathode materials via simple high-temperature calcination and electrochemical deposition methods. Because of the excellent specific capacity and conductivity of PANI, the CC@BCN@PANI core-shell nanoarrays cathode shows an excellent ion storage capability. Moreover, the 3D nanoarray structure can provide enough space for the volume expansion and contraction of PANI in the charging/discharging cycles, which effectively avoids the collapse of the microstructure and greatly improves the electrochemical stability of PANI. Therefore, the CC@BCN@PANI-based ZHSCs exhibit superior electrochemical performances showing a specific capacity of 145.8 mAh/g, a high energy density of 116.78 Wh/kg, an excellent power density of 12 kW/kg, and a capacity retention rate of 86.2% after 8000 charge/discharge cycles at a current density of 2 A/g. In addition, the flexible ZHSCs (FZHSCs) also show a capacity retention rate of 87.7% at the current density of 2 A/g after 450 cycles.

关键词： CC@BCN@PANI cathode     Zn-ion hybrid supercapacitor     core-shell nanoarrays     high energy density     ultra-high cycle stability    

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Preparation, with graphene, of novel biomimetic self-healing microcapsules with high thermal stability

《结构与土木工程前沿（英文）》   页码 1188-1198 doi: 10.1007/s11709-023-0027-5

摘要： This paper reports a comparative study of microcapsules with enhanced thermal stability and electrical conductivity inspired by the bionic thermal insulation of birds’ feathers for self-healing aged asphalt. The work is based on an in situ polymerization with composite shell components of graphene and hexamethoxymethylmelamine resin. By using graphene, microcapsules with rough surfaces are achieved, improving the interface between microcapsules and asphalt. In addition, the microcapsules’ initial thermal decomposition temperature is appropriately high, so that the stability of the microcapsule in the asphalt highway system is protected. The proportion of graphene in the microcapsule shell can regulate the microcapsule’s heat resistance because graphene modifies the shell’s structural makeup. Additionally, the microcapsules’ electrical conductivity is relatively high. The self-healing capability of bitumen sharply increases, providing benefit to the effect of microcapsules on the properties of aged asphalt.

关键词： graphene     microcapsule     bitumen     heat insulation     conductivity    

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On the seismic stability analysis of reinforced rock slope and optimization of prestressed cables

Wenbo ZHENG, Xiaoying ZHUANG, Yongchang CAI

《结构与土木工程前沿（英文）》 2012年 第6卷 第2期   页码 132-146 doi: 10.1007/s11709-012-0152-z

摘要： The evaluation of the seismic stability of high rock slopes is of vital importance to ensure the safe operation of the hydropower stations. In this paper, an equivalent pseudo-static force analysis based on the finite element method is developed to evaluate the seismic stability of reinforced rock slopes where the prestressed cables are modeled by the bar elements applied with nodal forces and bounded only at the anchored parts. The method is applied to analyze a high rock slope in south-west China and the optimization of cables. The stabilization effects of prestressed cables on the seismic stability of the slope are studied, the simulations of the concrete heading are discussed and the potential failure modes of the shear concrete plug are compared. Based on this, the optimization of cables is studied including the anchor spacing and inclined angles.

关键词： high rock slope     reinforced system     optimization     prestressed cable     seismicity    

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Rosin side chain type catalyst-free vitrimers with high cross-link density, mechanical strength, andthermal stability

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1267-1279 doi: 10.1007/s11705-022-2291-7

摘要： The emergence of vitrimer, a new class of polymer materials can address the problem of recyclability, reprocess ability and recyclability of thermosetting plastics. Rosin, a natural product, is an ideal raw material for the preparation of polymers in a more sustainable way. Nevertheless, due to the huge steric hindrance caused by the hydrogenated phenanthrene ring structure, the cross-link density of materials is frequently lowered. In this study, hydrogenated rosin was adopted for preparing hydrogenated rosin side-chain type diacids, which were reacted with mixed epoxy to obtain rosin side-chain type vitrimers. It was completely characterized by differential scanning calorimetry test, thermogravimetric analysis, shape memory test and self-healing test. The prepared vitrimers exhibited good self-healing properties, excellent heat resistance (Td = 352 °C) as well as high mechanical properties (tensile strength of 46.75 MPa). The tricyclic diterpene structure of rosin was introduced into the side chain in order to avoid the reduction of cross-link density resulting from the huge steric hindrance of the rigid tricyclic hydrophenylene skeleton. Vitrimers can undergo dynamic transesterification reaction without external catalysts due to the autocatalytic effect of tertiary amines from epoxy. Moreover, our work expanded the application field of rosin, increased the added value of rosin, and provided a novel method for preparing rosin-based vitrimers with ideal properties.

关键词： vitrimers     rosin     catalyst-free     high mechanical properties     dynamic transesterification reaction    

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层状岩质高边坡稳定监测技术

陈志坚

《中国工程科学》 2001年 第3卷 第5期   页码 86-91

摘要：

以江阴大桥南塔区层状岩质高边坡及地基基础安全监测为例，阐述其安全监测设计的原则、监测网点的合理布置、破碎边坡岩体中测斜孔埋设技术以及边坡稳定安全监控模型的建立。提出基于外部变形观测成果的边坡稳定性判别准则，基于剪切位移、桩基轴力和水平推力观测成果的边坡稳定安全裕度定量评价方法。

关键词： 江阴大桥     塔墩     边坡稳定     监测     测斜孔     监控模型    

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Parameter identification of interconnected power system frequency after trip-out of high voltage transmission

Xuzhan ZHOU,Shanshan LIU,Mingkun WANG,Yiping DAI,Yaohua TANG

《能源前沿（英文）》 2014年 第8卷 第3期   页码 386-393 doi: 10.1007/s11708-014-0323-9

摘要： Accurate modeling and parameters of high voltage (HV) grid are critical for stability research of system frequency. In this paper, simulation modeling of the system frequency was conducted of an interconnected power system with HV transmission lines in China. Based on recorded tripping data of the HV transmission lines, system parameters were identified by using genetic algorithm (GA). The favorable agreement between simulation results and recorded data verifies the validity of gird models and the accuracy of system parameters. The results of this paper can provide reference for the stability research of HV power grid.

关键词： high voltage (HV) grid     frequency stability parameter identification     primary frequency regulation (PFR)    

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CuAlCl

Yixiu WANG,Chao LI,Fanchao MENG,Shuling LV,Jintao GUO,Xiaoqin LIU,Chongqing WANG,Zhengfei MA

《化学科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 340-345 doi: 10.1007/s11705-014-1438-6

摘要： A CuAlCl doped metal organic framework, CuAlCl @MIL-101, was prepared by introducing CuAlCl into the pores of MIL-101 for the selective adsorption of CO over N . The CuAlCl molecules were evenly distributed into various pores sizes and did not change the intrinsic structure of the MIL-101. Isotherms for CO and N adsorption at 298 K showed that the CO capacity on CuAlCl @MIL-101 was much higher than that on virgin MIL-101, whereas the N capacity decreased. The selectivity for CO over N improved from 4.64 to 31.5 at 298 K and 1 bar. The CuAlCl @MIL-101 adsorbent displayed outstanding CO adsorption stability and the adsorbent could be regenerated by applying a simple vacuum of 4 mmHg.

关键词： metal organic framework     CO adsorbent     high stability     high selectivity     CuAlCl4    

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Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

《化学科学与工程前沿（英文）》 2022年 第16卷 第4期   页码 484-497 doi: 10.1007/s11705-021-2074-6

摘要： The nanocomposites of flower-like nickel phyllosilicate particles incorporated into epoxy resin were fabricated via an in-situ mixing process. The flower-like nickel phyllosilicate particles were firstly synthesized using a mild self-sacrificial templating method, and the morphology and lamellar structure were examined carefully. Several properties of mechanical, thermal and tribological responses of epoxy nanocomposites were performed. It was demonstrated that adequate flower-like nickel phyllosilicate particles dispersed well in the matrix, and the nanocomposites displayed enhanced tensile strength and elastic modulus but decreased elongation at break as expected. In addition, friction coefficient and wear rate were increased first and then decreased along with the particle content, and showed the lowest values at a mass fraction of 5%. Nevertheless, the incorporated flower-like nickel phyllosilicate particles resulted in the continuously increasing thermal stability of epoxy resin (EP) nanocomposites. This study revealed the giant potential of flower-like particles in preparing high-quality EP nanocomposites.

关键词： nickel phyllosilicate     flow-like structure     mechanical property     thermal stability     tribological performance    

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非线性系统高阶微分反馈控制

齐国元,陈增强,袁著祉

《中国工程科学》 2003年 第5卷 第8期   页码 35-44

摘要： 基于这种思想设计了能高品质地提取量测信号的微分和高阶微分的高阶微分器（HOD, high order differentiator），该HOD参数少，容易调节，并给出其稳定性、收敛性和滤波特性的证明；另外，对带有未知扰动、模型未知的非线性SISO和MIMO系统分别设计了基于HOD的高阶微分反馈自适应控制器（HODFC, high order differentials feedback adaptive

关键词： 高阶微分器     高阶微分反馈控制器     稳定性     鲁棒性     解耦控制    

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Stability analysis of a high loess slope reinforced by the combination system of soil nails and stabilization

Jiu-jiang WU,Qian-gong CHENG,Xin LIANG,Jian-Lei CAO

《结构与土木工程前沿（英文）》 2014年 第8卷 第3期   页码 252-259 doi: 10.1007/s11709-014-0260-z

摘要： While the soil nails and the corresponding compound technology are widely used as the support techniques for deep foundation pit and normal slopes, few related engineering cases are found for high loess slopes. By utilizing the finite element software of PLAXIS 8.5, the behavior of a high loess slope reinforced by the combination of soil nails and stabilization piles (hereinafter for CSNSP) is studied in this paper. It can be found that the potential slide surface of the slope moves to deeper locations during the process of the multi-staged excavations. The measure of reducing the weight of the top of the slope is a positive factor to the stability of the loess slope, while the rainfall is a negative factor. The slope can’t be stable if it’s reinforced only by stabilization piles or soil nails during the process of the multi-staged excavations. The soil nail contributes greater to the overall system stability when the excavation depth is relatively shallow, while the stabilization pile takes it over when the excavation depth reaches a large value. Compared to the results from the Sweden circular slip surface, the data derived from the method of phi/c reduction is relatively large when the slope is unreinforced or reinforced only by stabilization pile, and the data turns to be small when the slope is strengthened by soil nails or the combination system of soil nails and stabilization piles.

关键词： high loess slope     CSNSP     PLAXIS     phi/c strength reduction method     Sweden circular slip surface    

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东露天选煤厂槽仓高边坡稳定性与变形分析

姜海波,宫守才,刘庆雪

《中国工程科学》 2012年 第14卷 第2期   页码 107-112

摘要：

平朔东露天槽仓为目前亚洲最大规模的储煤槽仓。采用极限平衡方法和有限元法，开展了边坡在支护前后不同工况下的稳定性计算和应力与变形分析。结果表明，边坡支护前无法达到使用要求，斜壁与直壁转角处和仓底坡脚处为应力集中和变形最大处，是加固的重点部位。边坡采用土钉墙复合结构和灌注桩+钢内撑复合结构支护后，稳定性满足使用要求，变形在正常范围内，该支护方案非常适合该边坡。

关键词： 槽仓     边坡     极限平衡法     有限元法     稳定性     变形    

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Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 220-230 doi: 10.1007/s11705-017-1624-4

摘要： Clindamycin phosphate (CP), an antibacterial agent, has been reported to form several solid-state forms. The crystal structures of two CP solvates, a dimethyl sulfoxide (DMSO) solvate and a methanol/water solvate (solvate V), have been determined by single crystal X-ray diffraction. The properties and transformations of these forms were characterized by powder X-ray diffraction, Single-crystal X-ray diffraction, differential scanning calorimetry, thermo gravimetric analysis, hot-stage microscopy, and dynamic vapor sorption. Very different hydrogen bonding networks exist among the host-host and host-solvent molecules in the two crystal structures, resulting in different moisture stabilities. The thermal stabilities of the two solvates upon heating and desolvation were also studied. When the temperature was above the boiling point of methanol, solvate V converted to a polymorphic phase after a one step desolvation process, whereas the desolvation temperature of the DMSO solvate was below the boiling point of DMSO. At the relative humidity above 43%, the DMSO solvate transformed to a hydrate at 25 °C. In contrast, solvate V did not transform at any of the humidities studied.

关键词： clindamycin phosphate     solvate     crystal structure     thermal stability     moisture stability    

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A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

Cunyao Li, Wenlong Wang, Li Yan, Yunjie Ding

《化学科学与工程前沿（英文）》 2018年 第12卷 第1期   页码 113-123 doi: 10.1007/s11705-017-1672-9

摘要： Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffers from complicated operation and the difficulty in catalyst recycling. It is highly desirable to develop a heterogeneous catalyst that enables the catalyst recovery without sacrificing the activity and selectivity. There are two strategies to afford such a catalyst for the hydrofromylation: immobilized catalysts on solid support and porous organic ligand (POL)-supported catalysts. In the latter, high concentration of phosphine ligands in the catalyst framework is favorable for the high dispersion of rhodium species and the formation of Rh-P multiple bonds, which endow the catalysts with high activity and stability respectively. Besides, the high linear regioselectivity could be achieved through the copolymerization of vinyl functionalized bidentate ligand (vinyl biphephos) and monodentate ligand (3vPPh ) into the catalyst framework. The newly-emerging POL-supported catalysts have great perspectives in the industrial hydroformylation.

关键词： hydroformylation     porous organic ligand (POL)-supported catalysts     heterogeneous catalysis     high stability     immobilization catalysts    

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构建二维层状结构的稠环含能材料——高能量与高稳定性的平衡 Article

冯永安, 邓沐聪, 宋思维, 陈思同, 张庆华, Jean’ne M. Shreeve

《工程（英文）》 2020年 第6卷 第9期   页码 1006-1012 doi: 10.1016/j.eng.2020.01.013

摘要：

制造具有良好机械感度的高性能含能材料在过去几十年里一直是一项重大挑战，因为这类蕴含巨大能量的材料存在内在的不稳定性。本文研究了一种极具潜力的稠环含能材料：4-硝基-7-叠氮基-吡唑-[3,4-d]-1,2,3-三嗪-2-氧（NAPTO）。这种物质具有不同寻常的二维（2D）层状结构，其绝对结构已经单晶X射线衍射证实。研究显示，这一结构新颖的含能物质具有惊人的能量[如爆速（D）高达9.12 km·s–1，爆压（P）为35.1 GPa]、优异的机械感度[撞击感度（IS）为18 J、摩擦感度（FS）为325 N、静电感度（EDS）为0.32 J]和良好的热分解温度（203.2 ℃），展示出高能量与低感度的双重优势。据我们所知，NAPTO是首个具有二维层状结构的稠环含能材料。与此同时，运用分子模拟分析了其在外界机械刺激下的稳定机制，结果表明，该含能材料超平的二维层状结构比其他结构更能有效地缓冲外界机械刺激，从而将作用在材料上的机械能转化为晶体的层间滑动与压缩。本研究从实验和理论两个方面揭示了稠环二维层状结构在制造先进含能材料方面的巨大潜力。

关键词： 含能材料     稠环杂环化合物     二维层状结构     高能量     稳定性     感度    

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Enhanced charge extraction for all-inorganic perovskite solar cells by graphene oxide quantum dots modified TiO layer

《化学科学与工程前沿（英文）》 2023年 第17卷 第5期   页码 516-524 doi: 10.1007/s11705-022-2238-z

摘要： All-inorganic cesium lead bromide (CsPbBr3) perovskite solar cells have been attracting growing interest due to superior performance stability and low cost. However, low light absorbance and large charge recombination at TiO2/CsPbBr3 interface or within CsPbBr3 film still prevent further performance improvement. Herein, we report devices with high power conversion efficiency (9.16%) by introducing graphene oxide quantum dots (GOQDs) between TiO2 and perovskite layers. The recombination of interfacial radiation can be effectively restrained due to enhanced charge transfer capability. GOQDs with C-rich active sites can involve in crystallization and fill within the CsPbBr3 perovskite film as functional semiconductor additives. This work provides a promising strategy to optimize the crystallization process and boost charge extraction at the surface/interface optoelectronic properties of perovskites for high efficient and low-cost solar cells.

关键词： all inorganic     perovskite solar cells     graphene oxide quantum dots     high performance     stability    

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标题 作者 时间 类型 操作

CC@BCN@PANI core-shell nanoarrays as ultra-high cycle stability cathode for Zn-ion hybrid supercapacitors

期刊论文

Preparation, with graphene, of novel biomimetic self-healing microcapsules with high thermal stability

期刊论文

On the seismic stability analysis of reinforced rock slope and optimization of prestressed cables

Wenbo ZHENG, Xiaoying ZHUANG, Yongchang CAI

期刊论文

Rosin side chain type catalyst-free vitrimers with high cross-link density, mechanical strength, andthermal stability

期刊论文

层状岩质高边坡稳定监测技术

陈志坚

期刊论文

Parameter identification of interconnected power system frequency after trip-out of high voltage transmission

Xuzhan ZHOU,Shanshan LIU,Mingkun WANG,Yiping DAI,Yaohua TANG

期刊论文

CuAlCl

Yixiu WANG,Chao LI,Fanchao MENG,Shuling LV,Jintao GUO,Xiaoqin LIU,Chongqing WANG,Zhengfei MA

期刊论文

Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance

期刊论文

非线性系统高阶微分反馈控制

齐国元,陈增强,袁著祉

期刊论文

Stability analysis of a high loess slope reinforced by the combination system of soil nails and stabilization

Jiu-jiang WU,Qian-gong CHENG,Xin LIANG,Jian-Lei CAO

期刊论文

东露天选煤厂槽仓高边坡稳定性与变形分析

姜海波,宫守才,刘庆雪

期刊论文

Solvates and polymorphs of clindamycin phosphate: Structural, thermal stability and moisture stability

Junbo Gong, Dejiang Zhang, Yuanyuan Ran, Keke Zhang, Shichao Du

期刊论文

A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

Cunyao Li, Wenlong Wang, Li Yan, Yunjie Ding

期刊论文

构建二维层状结构的稠环含能材料——高能量与高稳定性的平衡

冯永安, 邓沐聪, 宋思维, 陈思同, 张庆华, Jean’ne M. Shreeve

期刊论文

Enhanced charge extraction for all-inorganic perovskite solar cells by graphene oxide quantum dots modified TiO layer

期刊论文